Download e-book for iPad: Chemical Physics of Intercalation by Albert Hérold (auth.), A. P. Legrand, S. Flandrois (eds.)

By Albert Hérold (auth.), A. P. Legrand, S. Flandrois (eds.)

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Herold, J. Chim. Phys. (1969)71 8. D. Guerard, A. Herold, Carbon 13 (1975)337 9. D. Guerard, M. Chaabouni, P. Lagrange, M. El Makrini, A. Herold, Carbon, 18 (1980)257 10. M. El Makrini, D. Guerard, P. Lagrange, A. Herold, ibid p203 11. D. Billaud, E. F. Mareche, A. Herold, Synth. Met. 3 (1981)21 12. S. Basu, C. Zeller, P. D. D. E. Fischer, Mater. Sci. Eng. 38 (1979)275 13. A. Herold, D. Saehr, Bull. Soc. Chim. Fr. (1960) 1039 14. D. Billaud, A. Herold, Bull. Soc. Chim. Fr. (1972) 103, and (1974) 2402 and 2407 15.

Magnetic measurements [40] have shown that the intercalated species are MF6 molecules associated with MF6- ions containing the metal M at the oxidation state V. In the corresponding formula Cnx +(MF6)x-(MF6) I-x' the value of x linearly increases with the electronic affinity of the MF6 molecules, which is given in the following table. The relatively small value of WF6 affinity explains that this compound does not intercalate by itself. 26 Table 7. Electronic affinities of MF6 molecules in eV according to Bartlett and Mc Quillan [41] Mo 1.

Schulze, O. Rubish, Z. Anorg. Allg. Chern, 282 (1955) 223 26. W. Rudorff, Chimia, 19 (1965)489 27. W. Craven, W. Ostertag, Carbon (1966)223 28. Stein, L. Bonnetain, J. Gole, Bull. Soc. Chim. Fr. (1966)3166 29. L. Bonnetain, Ph. Touzain, A. Hamwi, ISGIC 1, in Mat. Sc. Eng. 31 (1977)45 30. F. Beguin, P. Marceau, R. F. Quinton, Proc. 16th Bienn. Conf. on Carbon, San Diego, USA (1983)252 31. F. Beguin, H. Estrade-Szwarckopf, J. Conard, P. Lauginie, P. Marceau, D. Guerard, L. Facchini, ISGIC 3, in Synth.

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